We present results of recent studies of new materials designed for the additive manufacturing of accelerating structures for dielectric laser accelerators (DLAs). Demonstration of a stand-alone practical DLA requires innovation in design and fabrication of efficient laser accelerator structures and couplers. Many complicated three-dimensional structures for laser acceleration (such as a long woodpile structure with couplers) are difficult to manufacture with conventional microfabrication technologies. LANL has a large effort focused on developing new materials and techniques for additive manufacturing. The materials for DLA structures must have high dielectric constant (larger than 4), low loss in the infrared regime, high laser damage threshold, and be able to withstand the electron beam damage. This presentation will discuss the development of novel infrared dielectric materials that are of interest for laser acceleration and are compatible with additive manufacturing, as well as recent advances in additive manufacturing of dielectric woodpile structures using a Nanoscribe direct laser-writing 3D printer. Show Partial Abstract